
Cristiane Aparecida Martins
Research Lines
- • Combustion and propulsion
Publications (37)
High-pressure combustion of realistic landfill gas: Laminar burning velocity, Markstein length, and chemical-kinetic analysis of CH4–CO2–N2 mixtures
da Gama Leite, Haussman Guimarães , Martins, Cristiane Aparecida , Pizzuti, Loreto , Malatesta, Vinicius
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© 2026 The Author(s).Landfill gas (LFG) is a renewable yet highly diluted fuel whose variable composition and operation at elevated pressures pose significant challenges for stable and efficient combustion. In this work, the laminar burning velocity (LBV) and Markstein length of realistic CH4–CO2–N2 mixtures were investigated experimentally and numerically at 298 K, at pressures up to 5 bar, and for equivalence ratios ranging from 0.6 to 1.3, with special focus on the lean region where new burners concepts are expected operate and where data is quite scarce. Two surrogate fuels containing 65% and 55% CH4 were formulated while maintaining a constant CO2:N2 ratio to isolate the effect of total dilution. Experimental LBVs were determined using the outwardly propagating spherical flame method and compared with detailed chemical-kinetic mechanisms. Among the mechanisms evaluated, Konnov Mech 0.6 provided the best agreement with experimental data at 1 bar. The results show that increasing pressure and dilution both significantly reduce the LBV; however, they act through distinct mechanisms. Dilution primarily suppresses flame propagation through thermal effects, reducing adiabatic flame temperature and overall reaction rates, whereas pressure enhances competition between chain-branching and termination reactions, leading to reduced radical concentrations. Sensitivity and pathway analyses identified the reaction H + O2 ⇌ O + OH as the dominant promoting step controlling flame propagation under all conditions. The Markstein length was found to increase from lean to rich mixtures and to decrease with increasing pressure, indicating enhanced flame instability at elevated pressures. The present study provides new high-pressure experimental data and a detailed mechanistic interpretation of LFG combustion, contributing to improved modeling and the design of energy systems operating with low-calorific-value fuels.
Exploring limonene combustion through laminar burning velocity measurements and Markstein length for next-generation SAFs
Marcondes Garzón Lama, Luis Fernando , Vicente, Jônatas , da Gama Leite, Haussman Guimarães , Malatesta, Vinicius , Boschi Gonçalves, Rene Francisco , Martins de Oliveira Junior, Amir Antônio , Martins, Cristiane Aparecida
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© 2026 The Author(s).Sustainable aviation fuels (SAFs) are a critical pathway for reducing carbon dioxide (CO2) emissions from the aviation sector, yet the deployment of new SAF candidates requires a robust understanding of their fundamental combustion behavior. Limonene, a renewable terpene derived from pine and citrus biomass, has emerged as a promising candidate due to its favorable energy content and bulk properties relative to conventional Jet A-1. However, despite increasing interest, fundamental premixed combustion data for limonene—particularly laminar burning velocity and flame stability parameters—remain limited. The aim of this study is to address this gap through an experimental investigation of the premixed combustion characteristics of limonene. Laminar burning velocity measurements were performed in spherical and cylindrical constant-volume reactors at atmospheric pressure and unburned-gas temperatures of 358, 398, and 438 K using Schlieren imaging. Experiments were conducted for pure limonene, the Jet A-1 surrogate fuel MURI-1, and a 70/30 (vol./vol.) MURI-1–limonene blend over equivalence ratios from 0.7 to 1.4. The results show that pure limonene exhibits high laminar burning velocities, reaching peak values of approximately 70 cm s⁻1, exceeding those of conventional kerosene surrogates. Flame stability analysis reveals that limonene flames become increasingly sensitive to stretch under fuel-rich conditions, as indicated by decreasing Markstein length and Lewis number. Blending limonene with MURI-1 yields intermediate burning velocities and improves flame stability through increased Markstein length, despite a modest reduction in flame thickness, with enhancements of up to 8% observed under rich conditions. These findings provide new fundamental combustion data for limonene and demonstrate combustion trends consistent with other SAF candidates, supporting its potential as a viable component for future ASTM-certified sustainable aviation fuel formulations and for the development of validated chemical-kinetic models.
STATE OF THE ART OF INSPECTION PROCESSES FOR PIPES AND ACCESSORIES IN THE GREEN HYDROGEN INDUSTRY IN BRAZIL
da Silva, Cesar Augusto Francisco , Godoy Júnior, Ederaldo , Martins, Cristiane Aparecida
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© 2024, ETA-Florence Renewable Energies. All rights reserved.The green hydrogen industry is gaining momentum globally as a carrier of clean, sustainable energy with the potential to significantly reduce greenhouse gas emissions. Brazil, with its vast renewable energy resources and commitment to decarbonization, is emerging as a promising player in the green hydrogen market. As Brazil’s green hydrogen infrastructure expands, ensuring the safety and reliability of pipelines and accessories becomes crucial. This research provides an overview of the state of the art in pipeline and accessory inspection processes in the green hydrogen industry in Brazil, highlighting the advances and challenges faced in this rapidly evolving sector. It can also contribute to a better understanding of current knowledge about inspections in the green hydrogen transport network and how the collaboration of actors involved in the process of building international and national scientific knowledge is being carried out.
Thermodynamic Evaluation of the Energy Self-Sufficiency of the Tyre Pyrolysis Process
Gamboa, Alexander A.R. , dos Santos, Leila R. , Martins, Cristiane A. , Rocha, Ana M.A. , Alvarado-Silva, Carlos A. , de Carvalho, João A.
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© 2023 by the authors.The aim of this paper is to evaluate the energy self-sufficiency of the tyre pyrolysis process using the pyrolysis gas produced as a heat source. Experimental data on the properties of the tyre and the main pyrolysis products (char, pyrolysis gas, and condensable vapours) have been compiled for a pyrolysis temperature range from 698 to 848 K. The laws of thermodynamics were used to calculate the energy demand of the tyre pyrolysis process, which was divided into heat for the pyrolysis reaction and heat transferred to the carrier gas. The pyrolysis gas was composed of 15 components, and its composition was calculated using a nonstoichiometric equilibrium model. For the temperature range studied, the heat required for the pyrolysis reaction was between 1.41 and 2.16 kJ/g of tyre. In addition, hydrocarbons (71 to 73 wt.%) were the major components in the calculated pyrolysis gas composition. An average lower heating value of 37.3 MJ/kg was calculated for the pyrolysis gas. The heat required for the tyre pyrolysis reaction was provided for burning 30–50% of the pyrolysis gas produced, thus making it self-sustaining. Energy self-sufficiency may not be achieved if the heat losses due to poor reactor insulation are high. However, this problem can be overcome by heating the combustion air using the heat released by the pyrolysis products during cooling.
Performance Comparison of Paraffin/Ethanol Fuel Blends in a Laboratory-Scale Hybrid Rocket Motor
Martins, Paulo G.C. , de Souza, Kesiany M. , Boschi, Rene F. , Gouvêa, Leonardo H. , Martins, Cristiane A.
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© 2023 by the authors.This paper discusses the performance characteristics of a paraffin-based blend of liquid ethanol with paraffin as compared to pure paraffin in a hybrid rocket motor. Since the disclosure of the high regression rates of liquefying fuels as compared to classic fuels such as hydroxyl-terminated polybutadiene (HTPB), many studies using paraffin have been reported in the literature. Although pure paraffin regresses three to four times faster than HTPB, it is not an ideal fuel for launcher applications for the following reasons: it does not provide the optimum mechanical strength, it may suffer from combustion instability, and it offers low combustion efficiency. The proposed blend is biphasic, with drops of liquid ethanol trapped in a paraffin binder; and a nonionic surfactant was employed to emulsify the ethanol into paraffin wax. The results indicated that at a mean prefiring O∕F of 0.6 and a Gox of 60, both the P95E05 and P90E10 fuels demonstrated no significant statistical difference compared to pure paraffin in terms of thrust, specific impulse, fuel mass flow rate, characteristic velocity, and combustion efficiency. However, the P95E05 and P90E10 fuels did show damping in the pressure oscillations relative to paraffin, indicating a reduction in the low-frequency combustion instability observed in the ballistic responses of paraffin.
Statistical analysis of the uniformity of sprays of tire pyrolysis oil-diesel oil blends
Gamboa, Alexander A.R. , dos Santos, Leila R. , Martins, Cristiane A. , Chumpitaz, German R.A. , Andrade, José C.de , de Carvalho, João A.
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© 2023, The Author(s), under exclusive licence to The Brazilian Society of Mechanical Sciences and Engineering.Tire pyrolysis oil (TPO) shows promise as alternative fuels, not only for the raw material from which they can be produced (waste tires), but also their physical characteristics. In this work, the atomisation quality of TPO and its blends with diesel oil was evaluated from a statistical perspective. A 35 kW Y-jet atomiser, operating at an air-fuel mass ratio (AFR) in the range of 0.075 to 0.150, was used to produce the fuel sprays. The Log-Normal density function was used to describe the droplet size distribution of the sprays. Additionally, the d2-law was integrated into the density function to simulate TPO spray evaporation. The results showed that the increase in TPO in the fuel blend decreased the uniformity of droplet sizes in the spray, as well as increased the presence of larger droplets. However, operating the atomiser at a AFR = 0.150 reduced the presence of larger droplets and increased the volume fractions of smaller droplets.
Experimental investigation of hydrous ethanol/air flame front instabilities at elevated temperature and pressures
Gárzon Lama, Luis Fernando Marcondes , Pizzuti, Loreto , Sotton, Julien , Martins, Cristiane A.
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© 2020 Elsevier LtdThe present work experimentally investigates hydrous ethanol/air flame stability. The experimental data were obtained using spherically expanding flames in a constant volume bomb with optical access for high-speed schlieren photography. It explores the effect of flame parameters, such as thermal expansion rate, flame thickness, activation energy, and effective Lewis numbers, on flame dynamics at elevated pressures (2 to 6 bar) and temperatures (380 and 450 K), at various equivalence ratios (0.6 to 1.3) and water dilution contents (0, 5, 20 and 30% in volume). Adding water to the ethanol/air mixture and increasing its content leads to a significant decrease in flame instability, reducing the thermal expansion ratio while increasing the flame thickness and therefore reducing the propensity of hydrodynamic instability appearance on the flame front. The equivalence ratio has a significant effect on flame stability as well. Slightly rich mixtures present the maximum thermal expansion ratio and minimum flame thickness, therefore, presenting the highest propensity for hydrodynamic instability of the flame front. Besides, the effective Lewis number significantly decreases with equivalence ratio, showing a higher propensity of diffusional-thermal instability for rich mixtures. The flame front instability significantly increases with the mixture initial pressure, which results from the enhancement of the hydrodynamic instability due to the significant decrease in the flame thickness for all equivalence ratios. The initial temperature has a weaker effect on flame stability compared to the other thermo-chemical properties investigated. However, the flame front instability slightly increases with temperature.
Use of artificial neural networks to correct computer simulations of small-scale propellers
E Souza, Lucas Guimarães , Martins, Cristiane Aparecida , Sêcco, Ney Rafael
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© 2021, American Institute of Aeronautics and Astronautics Inc.. All rights reserved.Propellers are one of the most efficient ways to generate propulsion for low-speed flights. About 84% of the energy generated by the engines is utilized, being therefore widely used in several different aircraft. However, studies show that propellers with a diameter less than 16 inches have efficiency reduced by up to 15% when compared to larger ones. This deficiency is not always captured by the mathematical models, since they are not as accurate for that scale. The present study aims to increase the accuracy of simulations performed by a blade element/vortex software to predict the performance of different motor-propeller assemblies. For this purpose, neural networks are trained to correct thrust and torque values given by the software in relation to wind tunnel tests. For this, 28 propellers from different manufacturers and geometries are tested in wind tunnel and simulated in the software under the same conditions to generate the training database. Geometric data of propellers and operational conditions were used as inputs for the neural networks. The outputs are the difference between the results of the test in a wind tunnel and the software simulation. The use of neural networks to correct the simulation results reduced the mean squared error of the estimates at least in 80% in the case of thrust and 70% in the case of torque.
Measuring battery discharge characteristics for accurate UAV endurance estimation
Mariga, L. , Silva Tiburcio, I. , Martins, C. A. , Almeida Prado, A. N. , Nascimento, C.
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© 2020 Royal Aeronautical Society.The increasing use of unmanned aerial vehicles in areas such as rescue, mapping, and transportation have made it necessary to study more accurate techniques for calculating flight time estimates. Such calculations require knowing the battery discharge profile. Simplified flight time calculation methods provide data with uncertainties as they are based solely on manufacturer datasheet information. This study presents a setup to measure the battery discharge curve using a LabVIEW interface with a low-cost acquisition system. The acquired data passes through a nonlinear optimisation algorithm to find the battery coefficients, which enables the more precise estimation of its range and endurance. The great advantage of this model is that it makes it possible to predict how the battery will discharge at different rates using just one experimental curve. The methodology was applied to three different batteries and the model was validated with different discharge rates in a controlled environment, which resulted in endurance lower than 3.0% for most conditions and voltage estimation error lower than 3.0% in operational voltage. The work also presented a methodology for estimating cruise time based on the current used during each flight stage.
Experimental laminar burning velocity of syngas from fixed-bed downdraft biomass gasifiers
Oliveira, Guthman Palandi , Sbampato, Maria Esther , Martins, Cristiane Aparecida , Santos, Leila Ribeiro , Barreta, Luiz Gilberto , Boschi Gonçalves, Rene Francisco
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© 2020 Elsevier LtdLaminar burning velocity is considered as being one of the fundamental properties of a premixed flame and reliable data are constantly required for practical applications. Although it is possible to find an extensive amount of experimental laminar burning velocity data for fuels containing one or two components, data for fuels with three or more components are scarce. The goal of this study is to help fill this gap by providing experimental laminar burning velocity data for a fuel mixture with five components (H2:CO:CO2:CH4:N2). The fuel composition utilized is proposed as surrogates of the fuel provided by a downdraft gasifier, the most common and the most efficient type of gasifier. Experimental measurements were carried out for different fuel-to-air equivalence ratios (0.88 < ϕ < 1.74) at atmospheric conditions, 954 mbar and 298 K. The method utilized was the conical-flame surface using OH PLIF images (Planar-Laser-Induced Fluorescence imaging of OH). The area method provides a good approximation of the unstretched laminar burning velocity. Experimental data were compared with the simulated results obtained from a CHEMKIN chemical kinetics software. The highest experimental laminar flame speed of a downdraft syngas air mixture was 0.3491 m s−1 and occurred when ϕ ∼1.3.
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Supervisions (18 master's, 8 phd)
Luis Fernando Marcondes Garzón Lama (2025) PhD
Mayara Lopes Salgado (2025) Master's
Paulo Gabriel Cunha Martins (2024) PhD
Eduardo de Albuquerque Cavalcanti Filho (2023) Master's
Hermano Kehrle Miranda (2023) Master's
Haussman Guimarães da Gama Leite (2022) Master's
Emerson Andrade dos Santos (2022) PhD
Paulo Gabriel Cunha Martins (2020) Master's
Luis Fernando Marcondes Garzón Lama (2020) Master's
Lucas Guimarães e Souza (2020) Master's
